Volume 21, Issue 1 (4-2013)                   www.ijcm.ir 2013, 21(1): 1-4 | Back to browse issues page

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Synthesis and crystal structure of Zinc (II) Complex [Zn(25-MBTSC)2I2]. www.ijcm.ir 2013; 21 (1) :1-4
URL: http://ijcm.ir/article-1-340-en.html
Abstract:   (4065 Views)

Zinc (II) complex, [Zn(25-MBTSC)2I2] (1), where (25-MBTSC = (E)-2-(2,5-dimethoxybenzaldehyde) thiosemicarbazone, has been synthesized from the reaction of ZnI2 with 25-MBTSC in methanol as solvent at 25 ºC. It was characterized by elemental analysis (CHN) and is confirmed by single-crystal X-ray diffraction analysis. The complex 1 crystallizes in a triclinic system, with space group P-ī, having one symmetry-independent Zn2+ ion coordinated in a distorted tetrahedral geometry by two S atoms of the 25-MBTSC ligand and by two I atoms. The thiosemicarbazone ligand 25-MBTSC acts as a monodentate ligand and coordinates via one S atom in η1-S bonding mode to the zinc center.

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Type of Study: Research | Subject: Special

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