Volume 26, Issue 2 (7-2018)                   www.ijcm.ir 2018, 26(2): 489-498 | Back to browse issues page


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Synthesis of magnetic hydroxyapatite nanocomposites and investigation of its structural and magnetic properties. www.ijcm.ir. 2018; 26 (2) :489-498
URL: http://ijcm.ir/article-1-1112-en.html
Abstract:   (220 Views)
: Hydroxyapatite (Ca10(PO4)6(OH)2) with the hexagonal crystal structure is the only identifiable mineral phase of bone. In this work, magnesium ferrite-hydroxyapatite nanocomposites were synthesized for the purpose of medical applications. The first step of this work is the synthesis of mesoporous hydroxyapatite nanorods via co-precipitation method in combination with micelles template. Non-ionic surfactant Pluronic P123 was used as a micelles template. At the second step, magnesium ferrite-hydroxyapatite nanocomposites were synthesized by the sonochemical method. The crystal structure of nanopowders was determined using X-ray diffraction pattern. Transmission electron microscopy was also applied for the morphology of the samples. From TEM image of the nanocomposite, it was observed that magnesium ferrite nanopaticles have spherical shape with diameter of about 8 nm on the surface of hydroxyapatite nanorods. Hysteresis loops (M-H) of magnesium ferrite nanoparticles and magnesium ferrite-hydroxyapatite nanocomposites were measured at room temperature by a vibrating sample magnetometer. The results revealed the superparamagnetic behavior of the produced nanostructures.
Full-Text [PDF 127 kb]   (71 Downloads)    
Type of Study: Research | Subject: Special
Received: 2018/07/7 | Accepted: 2018/07/7 | Published: 2018/07/7

References
1. [1] Köferstein R., Walther T., Hesse D., Ebbinghaus S.G., "reparation and characterization of nanosized magnesium ferrite powders by a starch-gel process and corresponding ceramics", Mater. Sci. 48 (2013) 6509-6518. [DOI:10.1007/s10853-013-7447-x]
2. [2] Liu H., Liu H., "Synthesis of nanosize quasispherical MgFe2O4 and study of electrochemical properties as the anode of lithium-ion batteries", J. Electron. Mater. 43 (2014) 2553-2558. [DOI:10.1007/s11664-014-3117-2]
3. [3] Su N.R., Lv N.R., Li M., Zhang X., Li M., Niu J., "Fabrication of MgFe2O4–ZnO heterojunction photocatalysts for application of organic pollutants", Mater. Lett. 122 (2014) 201-204. [DOI:10.1016/j.matlet.2013.12.106]
4. [4] Gherca D., Pui D., Nica V., Caltun O., Cornei N., "Eco-environmental synthesis and characterization of nanophase powders of Co, Mg, Mn and Ni ferrites", Ceram. Int. 40 (2014) 9599-9607. [DOI:10.1016/j.ceramint.2014.02.036]
5. [5] Hankare P., Jadhav S., Sankpal U., Patil R., Sasikala R., Mulla I., "Gas sensing properties of magnesium ferrite prepared by co-precipitation method", J. Alloys Compd. 488 (2009) 270-272. [DOI:10.1016/j.jallcom.2009.08.103]
6. [6] Gadkari A.B., Shinde T.J., Vasambekar P.N., "Nanocrystallite Mg ferrite LPG, Cl2 and C2H5OH sensor", in SOLID STATE PHYSICS: PROCEEDINGS OF THE 56TH DAE SOLID STATE PHYSICS SYMPOSIUM 2011, AIP Publishing, 2012, pp. 415-416. [DOI:10.1063/1.4710056]
7. [7] Mongia N., Srivastava A., Bansal D., Giri P., Goswami D., Perumal A., Chattopadhyay A., "Effect of pH on Magnetic and Structural Properties of Low Temperature Synthesized MgFe2O4 Nanoparticles, in AIP Conference Proceedings", 2010, pp. 394. [DOI:10.1063/1.3504333]
8. [8] Naseri M.G., Ara M.H.M., Saion E.B., Shaari A.H., "Superparamagnetic magnesium ferrite nanoparticles fabricated by a simple thermal treatment method", J. Magn. Magn. Mater. 350 (2014) 141-147. [DOI:10.1016/j.jmmm.2013.08.032]
9. [9] Yang H., Masse S., Zhang H., Hélary C., Li L., Coradin T., "Surface reactivity of hydroxyapatite nanocoatings deposited on iron oxide magnetic spheres toward toxic metals", J. Colloid Interface Sci. 417 (2014) 1-8. [DOI:10.1016/j.jcis.2013.11.031]
10. [10] Gopi D., Ansari M.T., Shinyjoy M.T., Kavitha L., "Synthesis and spectroscopic characterization of magnetic hydroxyapatite nanocomposite using ultrasonic irradiation", Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 87 (2012) 245-250. [DOI:10.1016/j.saa.2011.11.047]
11. [11] Ye F., Guo H., Zhang H., He X., "Polymeric micelle-templated synthesis of hydroxyapatite hollow nanoparticles for a drug delivery system", Acta Biomaterialia. 6 (2010) 2212-2218. [DOI:10.1016/j.actbio.2009.12.014]
12. [12] Singh R.K., El-Fiqi A.M., Patel K.D., Kim H.W., "A novel preparation of magnetic hydroxyapatite nanotubes", Mater. Lett. 75 (2012) 130-133. [DOI:10.1016/j.matlet.2012.01.129]
13. [13] Li P., Li L., Zhao Y., Sun L., Zhang Y., "Selective binding and magnetic separation of histidine-tagged proteins using Fe3O4/Cu-apatite nanoparticles", J. Inorg. Biochem. 156 (2016) 49-54. [DOI:10.1016/j.jinorgbio.2015.12.017]
14. [14] Shan Z., Li X., Gao Y., Wang X., Li C., Wu Q., "Application of magnetic hydroxyapatite nanoparticles for solid phase extraction of plasmid DNA", Anal. Biochem. 425 (2012) 125-127. [DOI:10.1016/j.ab.2012.03.013]
15. [15] Liu Y., Zhong H., Li L., Zhang C., "Temperature dependence of magnetic property and photocatalytic activity of Fe3O4/hydroxyapatite nanoparticles", Mater. Res. Bull. 45 (2010) 2036-2039. [DOI:10.1016/j.materresbull.2010.09.010]
16. [16] Petchsang N., Pon-On W., Hodak J., Tang I., "Magnetic properties of Co-ferrite-doped hydroxyapatite nanoparticles having a core/shell structure", J. Magn. Magn. Mater. 321 (2009) 1990-1995. [DOI:10.1016/j.jmmm.2008.12.027]
17. [17] Pon-On W., Charoenphandhu N., Tang I.-M., Jongwattanapisan P., Krishnamra N., Hoonsawat R., "Encapsulation of magnetic CoFe2O4 in SiO2 nanocomposites using hydroxyapatite as templates: A drug delivery system", Materials Chemistry, and Physics, 131 (2011) 485-494. [DOI:10.1016/j.matchemphys.2011.10.008]
18. [18] Foroughi F., Hassanzadeh-Tabrizi S., Amighian J., Saffer-Teluri A., "A designed magnetic CoFe2O4–hydroxyapatite core–shell nanocomposite for Zn (II) removal with high efficiency", Ceram. Int. 41 (2015) 6844-6850. [DOI:10.1016/j.ceramint.2015.01.133]
19. [19] Yao S., Yan X., Zhao Y., Li B., Sun L., "Selective binding and magnetic separation of histidine-tagged proteins using Ni2+-decorated Fe3O4/hydroxyapatite composite nanoparticles", Mater. Lett. 126 (2014) 97-100. [DOI:10.1016/j.matlet.2014.04.022]
20. [20] Wakiya N., Yamasaki M., Adachi T., Inukai A., Sakamoto N., Fu D., Sakurai O., Shinozaki K., Suzuki H., "Preparation of hydroxyapatite–ferrite composite particles by ultrasonic spray pyrolysis", Mater. Sci. Eng., B. 173 (2010) 195-198. [DOI:10.1016/j.mseb.2009.12.013]
21. [21] Zhao Y., Ma J., "Triblock co-polymer templating synthesis of mesostructured hydroxyapatite", Microporous and Mesoporous Materials, 87 (2005) 110-117. [DOI:10.1016/j.micromeso.2005.07.046]
22. [22] Chandradass J., Jadhav A.H., Kim K.H., Kim H., "Influence of processing methodology on the structural and magnetic behavior of MgFe2O4 nanopowders", J. Alloys Compd. 517 (2012) 164-169. [DOI:10.1016/j.jallcom.2011.12.071]
23. [23] Salimi E., Javadpour J., Anbia M., "Template-based synthesis of nanoporous hydroxyapatite", ISRN Ceramics, 2012 (2012).
24. [24] Saeri M. R., Nilforoshan M., "Crystallography and morphological study of synthesized hydroxyapatite nano-particles", ijcm 1 (2006) 55-64.
25. [25] Arabi H., Moghadam N.K., "Nanostructure and magnetic properties of magnesium ferrite thin films deposited on glass substrate by spray pyrolysis", J. Magn. Magn. Mater. 335 (2013) 144-148. [DOI:10.1016/j.jmmm.2013.02.006]

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