Volume 30, Issue 2 (5-2022)
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Gholizadeh, Beyranvand, Zahedi. Microstructural, optical, and magnetic properties of Mn0.3-xBaxCu0.2Zn0.5Fe2O4 nanoparticles. www.ijcm.ir 2022; 30 (2) :28-28
URL: http://ijcm.ir/article-1-1755-en.html
URL: http://ijcm.ir/article-1-1755-en.html
Abstract: (1024 Views)
The effect of Ba ion substitution on structural, optical, and magnetic properties of Mn0.3-xBaxCu0.2Zn0.5Fe2O4 ferrites was investigated. The samples were characterized by X-ray diffraction, Fourier transform infrared spectroscopy, scanning electron microscopy, UV-Vis spectroscopy, and vibrating sample magnetometer at room temperature. Structural results show that the structure of the samples with x up to 0.20 is completely indexed to a single-phase cubic structure (space group Fd m), while the impurity phase of BaO is observed in the samples with x = 0.25, 0.30. As the substitution content increases, the presence of non-magnetic Ba2+ ions in the octahedral site decreases the saturation magnetization of the samples. Comparison of the bandgap energy of the samples shows an increasing trend with Ba substitution for x up to 0.10 and then decreases, which can be interpreted in terms of changes in the electronic structure of the samples.
Keywords: Mn-Cu-Zn spinel ferrite, citrate-nitrate method, X-ray diffraction, magnetic properties, optical properties.
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