Volume 27, Issue 1 (4-2019)                   www.ijcm.ir 2019, 27(1): 221-230 | Back to browse issues page

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Yeganeh M, Badieian Baghsiyahi F, Mousavi M. Investigation of structural and optical properties of Cr doped TiO2 synthesized at different annealing temperature by analyzing the XRD patterns and DRS spectroscopy. www.ijcm.ir 2019; 27 (1) :221-230
URL: http://ijcm.ir/article-1-1237-en.html
Abstract:   (2321 Views)
Extension of the optical response with the high efficiency in visible region of the solar light spectrum is one of the research goals of the photocatalysts based on TiO2. In this work, Cr doped TiO2 was synthesized by sol-gel method at different annealing temperature of 400, 600 and 800 oC in order to increase the optical absorption of TiO2. Upon increasing the annealing temperature, the anatase transformed to rutile while the size of the nanoparticles increased. Anatase was often used for investigation of photocatalytic activities and has been introduced as the desired phase of TiO2 for the photocatalytic applications. According to the observed increase in the optical absorption of the rutile by diffuse reflectance spectroscopy (DRS) and considering the structural properties of rutile, this phase of TiO2 can also be considered for photocatalytic activities and applications.
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Type of Study: Research | Subject: Special

1. [1] Yang H.G., Sun H.G., Qiao S.Z., Zou S.Z., Liu G., Smith G., Cheng G., Lu G.Q.,"Anatase TiO2 single crystals with a large percentage of reactive facets", Nature 453 (2008) 638. [DOI:10.1038/nature06964]
2. [2] He G.Q., Tilocca A., Dulub O., Selloni O., Diebold U., "Local ordering and electronic signatures of submonolayer water on anatase TiO2 (101)", Nature materials 8/7 (2009) 585. [DOI:10.1038/nmat2466]
3. [3] Virkutyte J., Baruwatia B., Varma R.S., "Visible light induced photobleaching of methylene blue over melamine-doped TiO2 nanocatalyst", Nanoscale 2 (2010) 1109. [DOI:10.1039/c0nr00089b]
4. [4] Matsumoto Y., Murakami Y., Shono Y., Hasegawa Y., Fukumura Y., Kawasaki M., Ahmet P., Chikyow T., Koshihara S.Y., Koinuma H., "Room-temperature ferromagnetism in transparent transition metal-doped titanium dioxide", Science 291 (2001) 854. [DOI:10.1126/science.1056186]
5. [5] Liang Y., Gan S., Chambers S., Altman E.I.," Surface structure of anatase TiO2 (001): Reconstruction, atomic steps, and domains", Phys. Rev. B 63 (2001) 235402. [DOI:10.1103/PhysRevB.63.235402]
6. [6] Vargas X., Tauchert E., Marin J.-M., Restrepo G., Dillert G., Bahnemann G., "Fe-doped titanium dioxide synthesized: Photocatalytic activity and mineralization study for azo dye", Journal of Photochemistry and Photobiology A: Chemistry 243 (2012) 17. [DOI:10.1016/j.jphotochem.2012.06.001]
7. [7] Ould-Chikh S., Proux O., Afanasiev P., Khrouz L., Hedhili M.N., Anjum D.H., Harb M., Geantet C., Basset J.M., Puzenat E., "Photocatalysis with chromium-doped TiO2 : bulk and surface doping", Chem. Sus. Chem. (2013) 1.
8. [8] Khorrami G., Mousavi M., "Effect of gelatin on structural properties of lead-free piezoelectric (K0.5Na0.5) NbO3 nanopowders synthesized by a modified sol-gel route in gelatin media", Iranian journal of Crystallography and Mineralogy, 25 (2017) 647-654.
9. [9] Wiliamson G.K., Hall W.H., "X-ray Line Broadening from Filed Aluminium and Wolfram", Acta Meatall 1 (1953) 22. [DOI:10.1016/0001-6160(53)90006-6]
10. [10] Maurya A., Chauhan P., Mishra S.K., Srivastava R.K., "Structural, optical and charge transport study of rutile TiO2 nanocrystals at two calcination temperatures", Journal of Alloys and Compound (2011) 8433. [DOI:10.1016/j.jallcom.2011.05.108]
11. [11] Prabu K.M., Perumal K.M., "Micro strain and Morphological studies of anatase and rutile TiO2 nanocrystals prepared via sol-gel and solvothermal method - A comparative study", IJSRSET 1/4 (2015) 299.
12. [12] Zhang H., Banfield J.F., "Understanding polymorphic phase transformation behavior during growth of nanocrystalline aggregates: insights from TiO2", J. Phys. Chem. B 104 (2000) 3481. [DOI:10.1021/jp000499j]
13. [13] Chen Q., Liu Q., Xin Q., Cheng X., "TiO2 nanobelts – Effect of calcination temperature on optical, photoelectrochemical and photocatalytic properties", Electrochimica Acta 111 (2013) 284. [DOI:10.1016/j.electacta.2013.08.049]
14. [14] Wu Q., Zheng Q., Krol R.,"Creating oxygen vacancies as a novel strategy to form tetrahedrally coordinated Ti4+ in Fe/TiO2 nanoparticles", J. phys. Chem. C 116 (2012) 7219. [DOI:10.1021/jp212577g]
15. [15] Li R., Guoa R., He R.,"The doping mechanism of Cr into TiO2 and its influence on the photocatalytic performance", Phys. Chem. Chem. Phys. 15 (2013) 20037. [DOI:10.1039/c3cp53531b]
16. [16] Loan R., Long R., "Optical properties of anatase and rutile TiO2:Cr3+ powders", VNU Journal of Science: Mathematics-Physics 30 (2014) 59.
17. [17] Yadav R., Kolekar T.V., Barge A.S., Thorat N.D., Delekar S.D., Kim S.D., Kim B.J., Kim B.J., Enhanced visible light photocatalytic activity of Cr3+-doped anatase TiO2 nanoparticles synthesized by sol–gel method", J Mater Sci: Mater Electron (2015).
18. [18] Bae S.W., Borse P.H., Hong P.H., Jang J.S., Lee J.S., Jeong J.S., Hong T.E., Yoon J.H., Jin J.S., Kim J.S., "Photophysical properties of nanosized metal-doped TiO2 photocatalyst working under visible light", Journal of the Korean Physical Society 51 (2007) S22. [DOI:10.3938/jkps.51.22]
19. [19] Diebold U., "The surface science of titanium dioxide", Surface Science Reports 48 (2003) 53. [DOI:10.1016/S0167-5729(02)00100-0]
20. [20] Mohamed S.M., El-Hagary M., Althoyaib S., "Growth of undoped and Fe doped TiO2 nanostructures and their optical and photocatalytic properties", Appl. Phys. A 111 (2013) 1207. [DOI:10.1007/s00339-012-7367-7]
21. [21] Shirpaei A., Malekfar R., "Shift and broadening investigation of Raman active phonons of TiO2 nanocrystallites at high temperatures", Iranian journal of Crystallography and Mineralogy, 17 (2009) 472-463.
22. [22] Tian B., Li C., Zhang J., One-step preparation, characterization and visible-light photocatalytic activity of Cr-doped TiO2 with anatase and rutile bicrystalline phases", Chemical Engineering Journal 191 (2012) 402. [DOI:10.1016/j.cej.2012.03.038]

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