دوره 26، شماره 2 - ( 4-1397 )                   جلد 26 شماره 2 صفحات 488-479 | برگشت به فهرست نسخه ها


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Synthesis, crystal-molecular structure and spectral investigation of mixed-ligand Cu(II) new complex with 1,10-phenanthroline bidentate ligand by Salicylaldehyde S-benzylisothiosemicarbazone. www.ijcm.ir 2018; 26 (2) :479-488
URL: http://ijcm.ir/article-1-1111-fa.html
محجوبی‌زاده میلاد، تکجو رضا، ت. مگ ژول. ساخت و بررسی ساختار بلوری-مولکولی و طیفی یک کمپلکس لیگاند-مخلوط جدید از مس(II) با لیگاند دو دندانه 1 و 10-فنانترولین به همراه سالیسیل آلدهید S-بنزیل ایزوتیوسمی‌کربازون. مجله بلورشناسی و کانی شناسی ایران. 1397; 26 (2) :479-488

URL: http://ijcm.ir/article-1-1111-fa.html


1- دانشگاه فردوسی مشهد
2- دانشگاه تولان
چکیده:   (3949 مشاهده)
کمپلکس لیگاند-مخلوط مس(II) از واکنش لیگاند سالیسیل آلدهید S-بنزیل ایزوتیوسمی­کربازون هیدروکلرید (H2Lنمک مس(II استات تک­آبه و 1و10-فنانترولین (Phen) با فرمول عمومی[Cu(Phen)2Cl].H2L,Cl,H2O  تهیه شد. ساختار آن به وسیله­ی تجزیه­ی عنصری و طیف­سنجی فروسرخ شناسایی شد و از پراش پرتوی X تک بلور به منظور شناخت بیشتر ساختار مولکولی کمپلکس مس(II) استفاده شد. در کمپلکس مس(II)، هندسه­ی هم­آرایی اطراف اتم مرکزی حدواسط بین هرم با قائده­ی مربعی و دوهرمی مثلثی است. دو لیگاند 1و10-فنانترولین (دهنده­ی NN) به صورت دو دندانه­ی خنثی، به فلز مرکزی همتافته شده است. جایگاه پنجم با اتم کلر اشغال شده است.     
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نوع مقاله: پژوهشي | موضوع مقاله: تخصصي

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