Volume 27, Issue 4 (12-2019)                   www.ijcm.ir 2019, 27(4): 967-974 | Back to browse issues page


XML Persian Abstract Print


Download citation:
BibTeX | RIS | EndNote | Medlars | ProCite | Reference Manager | RefWorks
Send citation to:

Tafreshi M, Solgi S, Sasani Ghamsari M. Synthesis & structural characterization of Yttrium calcium borate, compound, by one step solid- state reaction method. www.ijcm.ir 2019; 27 (4) :967-974
URL: http://ijcm.ir/article-1-1375-en.html
1- Semnan University
2- Photonics & Quantum Technologies Research School, Nuclear Science & Technology Research Institute
Abstract:   (2302 Views)
Yttrium calcium borate Y2CaB10O19 (YCB) compound is a new member of Rare Earth Borate compounds with nonlinear optical application. In the present research, the synthesis of YCB compound was investigated by using solid-state reaction method. Instead of usual preliminary and secondary thermal treatments, a single stage thermal process was developed. This new method is particularly important in terms of reducing the time and cost of synthesis. The structure of produced powder was analyzed by X-Ray diffraction and the powder x-ray data were also investigated by FullProf program. This Rietveld analysis confirmed the Hexagonal structure and P63/m space group, The bond angles were also reported. The anionic group and bond formation were studied using Raman spectroscopy. The results confirm both BO3 and BO4 formation. The Field emission scanning electron microscopy was carried out to study the morphology of the optimum sample.
Full-Text [PDF 112 kb]   (611 Downloads)    
Type of Study: Research | Subject: Special

References
1. [1] Yi Yang, Xingxing Jiang, Zheshuai Lin, Yicheng Wu, "Borate-based ultraviolet and deep-ultraviolet nonlinear optical crystals", Crystals 7 (2017) 1-16. [DOI:10.3390/cryst7040095]
2. [2] Shu Guo, Fei Liang, Lijuan Liu, Mingjun Xia, Zhi Fang, Ruofei Wu, Xiaoyang Wang, Zheshuai Lin, Chuangtian Chen, "LiSr3Be3B3O9F4: A New Ultraviolet Nonlinear Optical Crystal for Fourth-harmonic Generation of Nd: YAG Lasers", New Journal of Chemistry 37 (2017) 4269-4272. [DOI:10.1039/C7NJ00160F]
3. [3] Shiv Halasyamani P., Weiguo Zhang, "Viewpoint: Inorganic Materials for UV and Deep-UV Nonlinear Optical Applications", Inorganic Chemistry 56 (2017) 12077-12085. [DOI:10.1021/acs.inorgchem.7b02184]
4. [4] Selda Sari, Fatma Tugce Senberber, Meral Yildirim, Azmi Seyhun Kipcak, Sureyya Aydin Yuksel, Emek Moroydor Derun, "Lanthanum borate synthesis via the solid-state method from a La2O3 precursor: Electrical and optical properties", Materials Chemistry and Physics 200 (2017) 196 - 203. [DOI:10.1016/j.matchemphys.2017.07.056]
5. [5] Yicheng W., Jianguo LIU, Peizhen F., Junxing W., Fan G., Guiwen Z., "A New Class of Nonlinear Optical Crystals R2CaB10O19 (RCB)", Proceedings of the SPIE 3556 (1998) 8-13. [DOI:10.1117/12.318246]
6. [6] Junxin Wang, Peizhen Fu, Yicheng Wu, "Top-seeded growth and morphology of La2CaB10O19 crystals", Journal of Crystal Growth235(2002)5-7. [DOI:10.1016/S0022-0248(01)01927-3]
7. [7] Fangli Jing, Yicheng Wu, Peizhen Fu, "Growth of La2CaB10O Single crystals from Cao-Li2O-B2O3 flux", Journal of Crystal Growth 285 (2005) 270-274. [DOI:10.1016/j.jcrysgro.2005.08.030]
8. [8] Xu X. W., Chong T.C., Zhang G.Y., "Growth and optical properties of a new nonlinear optical lanthanum calcium borate crystal", Journal of Crystal Growth 237-239 (2002) 649-653. [DOI:10.1016/S0022-0248(01)02023-1]
9. [9] Senthilkumar M., Kalidasan M., Sugan, Dhanasekaran R., "Crystal growth of lanthanum calcium borate (LCB) single crystals from melt and its characterization", Journal of Crystal Growth 362 (2013) 202-206. [DOI:10.1016/j.jcrysgro.2012.07.044]
10. [10] Arun Kumar R., "Recent advances in rare earth-based borates single crystals: Potential materials for nonlinear optical and laser applications", Progress in Crystal Growth and Characterization of Materials 59 (2013) 113-132. [DOI:10.1016/j.pcrysgrow.2013.07.001]
11. [11] Xinyuan Zhang, Yang Wu, Yin Li, "Growth and spectroscopic properties of Sm-doped LCB crystal", Journal of Crystal Growth 399 (2014) 39-42. [DOI:10.1016/j.jcrysgro.2014.04.020]
12. [12] Szymborska Małek K., Ptak M., Tomaszewski P.E., Majchrowski A., "Raman and IR spectroscopic study of a nonlinear optical crystal, La2CaB10O19', Vibrational Spectroscopy, 82 (2016) 53-59. [DOI:10.1016/j.vibspec.2015.12.003]
13. [13] Faxian Shan, Ying Fu, Guochun Zhang, Tianxiang Xu, Xinyuan Zhang, Yicheng Wu, "Growth and spectroscopic properties of Tb3+ doped La2CaB10O19 crystal", Optical Materials, 49 (2015) 27-31. [DOI:10.1016/j.optmat.2015.08.020]
14. [14] Arun Kumar R., Arivanandhan M., Dhanasekaran R., Hayakawa Y., "Growth and characterization of a novel nonlinear optical borate crystal - Yttrium calcium borate (YCB)", Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 110 (2013) 391-394. [DOI:10.1016/j.saa.2013.03.069]
15. [15] Battiston S., Fanciulli C., Fiameni S., Famengo A., Fasolin S., Fabrizio M., "One step synthesis and sintering of Ni and Zn substituted tetrahedrite as thermoelectric material", Journal of Alloys and Compounds 702 (2017) 75-83. [DOI:10.1016/j.jallcom.2017.01.187]
16. [16] Co'rdoba J.M., Alcal'a M.D., Avil'es M.A., Sayagu'es M.J., Gotor F.J., "New production of TiCxN1-x -based cermets by one step mechanically induced self-sustaining reaction: Powder synthesis and pressureless sintering", Journal of the European Ceramic Society 28 (2008) 2085-2098. [DOI:10.1016/j.jeurceramsoc.2008.02.007]
17. [17] Gonzalez-Julian J., Onrubia S., Bram M., Guillon O., "Effect of sintering method on the microstructure of pure Cr2AlC MAX phase ceramics", Journal of the Ceramic Society of Japan 124 (2016) 415-420. [DOI:10.2109/jcersj2.15263]
18. [18] Zhang Y., Chen X.L., Liang J.K., Xu T., Xu Y.P., "Phase relations in the system Y2O3-CaO-B2O3", Journal of Alloys and Compounds 327 (2001) 132-135. [DOI:10.1016/S0925-8388(01)01556-0]
19. [19] Ray L. Frost, "Raman spectroscopy of selected borate minerals of the pinakiolit'e group", J. Raman Spectroscopy 42 (2011) 540-543. [DOI:10.1002/jrs.2745]
20. [20] Frost R. L., López A., Xi, Y., Graça, L. M., and Scholz, R., "A Vibrational Spectroscopic Study of The Borate Mineral Takedaite Ca3 (BO3)2", Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 132 (2014) 833-837. [DOI:10.1016/j.saa.2014.06.004]
21. [21] Janda R., Heller G., "IR- und Raman Spektren Isotop Markierter Tetra- und Pentaborate," Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 36 (1980) 997- 1001. [DOI:10.1016/0584-8539(80)80179-6]
22. [22] Xia Wang, Pan Liang, Hong-Sheng Huang, Zhi-Hong Liu, "Preparation of LaB3O6: Eu3+ phosphors by a facile precursor method and their luminescent properties", Materials Research Bulletin 52 (2014) 112-116. [DOI:10.1016/j.materresbull.2014.01.012]

Add your comments about this article : Your username or Email:
CAPTCHA

Rights and permissions
Creative Commons License This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License.

© 2024 CC BY-NC 4.0 | Iranian Journal of Crystallography and Mineralogy

Designed & Developed by : Yektaweb