AU - Soleimannejad, janet AU - Sedghiniya, sima AU - Nasibipour, mina TI - Synthesis and Crystal Structure of bis(3,3,5,5-tetramethyl benzidinium) bis(pyridine-2,6-dicarboxylato) nickelate(II) monohydrate PT - JOURNAL ARTICLE TA - ijcmir JN - ijcmir VO - 25 VI - 3 IP - 3 4099 - http://ijcm.ir/article-1-965-en.html 4100 - http://ijcm.ir/article-1-965-en.pdf SO - ijcmir 3 AB  - The compound of (Htmb)2[Ni(pydc)­2)].H2O (1) (In that tmb and pydc are 3,3¢,5,5¢-tetramethyl benzidine and pyridine -2,6- dicarboxylic acid, respectively) was synthesized via the proton transfer method and the structure was determined by single crystal X-ray diffraction. This compound crystalized in monoclinic crystal system and C2/c space group. In the asymmetry unit of compound 1, there are half molecule of the [Ni(pydc)­2)]2- anionic complex, one protonated molecule of 3,3¢,5,5¢-tetramethyl benzidine as a counter ion and half of an uncoordinated water molecule. Extensive intermolecular N-H…O and O-H…N, hydrogen bonds along with π… π and C-H …π interactions contribute in self-assembly and formation of a novel supramolecular structure. CP - IRAN IN - School of Chemistry, College of Science, University of Tehran, P.O. Box 14155-6455, Tehran, Iran LG - eng PB - ijcmir PG - 673 PT - Research YR - 2017