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Tondkar, Masoudi. Mineralogy, Raman spectroscopy and lattice parameter characterization of biotite with hexagonal structure from Borujerd hornfels and migmatites. www.ijcm.ir 2022; 30 (1) :11-11
URL: http://ijcm.ir/article-1-1719-en.html
Abstract:   (913 Views)
Biotite is a common rock-forming mineral and accepts a variety of elements in its structure. The valuable information of crystallization conditions of the biotite mineral obtain on natural biotite composition. The biotite mineral is one of the main mineral phases of pelitic rocks which are formed in a wide range of geological conditions. In this research, microscopic mineralogy, Raman spectroscopy, and X-ray diffraction of biotite minerals from hornfels and migmatites from the Borujerd granitoid aureole in the Sanandaj Sirjan zone investigated. On microscopic studies, mica crystals display common biotite characterizations but the mineral is uniaxial not biaxial as ordinary mica with a monoclinic system. Based on X-ray diffraction, the biotite crystals form in hexagonal crystalline habit. The Raman spectroscopy also reveals the variations in number and shifts on peaks in the range of 500 to 750 cm-1. Based on XRD data, the unit cell lattice parameters have revealed hexagonal mica crystals for the Borujerd migmatite and hornfels. Previous works reported temperatures in the range of 642 to 750 C° for the studied rocks. Investigation on synthetic biotite mineral suggests temperature above 700 C° for monoclinic to hexagonal transformation which confirm the formation of the high-temperature metamorphic event in the Borujerd region.
 
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References
1. [1] Wang A., Freeman J.J., Jolliff B.L., "Understanding the Raman spectral features of phyllosilicates", Journal of Raman Spectroscopy (2015). [DOI:10.1002/jrs.4680]
2. [2] Sheykhi M., Rezaei-Kahkhaei M., Ghasemi H.A., "Biotite and feldspar chemistry: An approach to the petrogenesis of the Gapdan pluton (NW of Zahedan) (in Persian)", Iranian Journal of Crystallography and Mineralogy 27 (3) (2019) 635-648. [DOI:10.29252/ijcm.27.3.635]
3. [3] Turkian A., "A study of geochemical behavior of whole-rock and mineral chemistry of Biotite and Feldspar in Shear zone, E-Qorveh (Kurdistan) (in Persian)", Iranian Journal of Crystallography and Mineralogy 21 (3) (2013) 581-594.
4. [4] Barahmand L., Rasouli J., Ghorbani M., "Biotite chemistry and thermobarometry of barren and productive intrusive bodies in Dehaj-Meiduk area (North Shahrbabak) (in Persian)", Iranian Journal of Crystallography and Mineralogy 24 (4) (2017) 799-812.
5. [5] Moazzen M., Torabi Asl S., Omrani H., "Study of pressure and temperature of metamorphism, phase stability and garnet and biotite chemical zoning in the Jandaq metamorphic rocks using pseudosection method (in Persian)", Iranian Journal of Crystallography and Mineralogy 23 (4) (2016) 651-660.
6. [6] Sadati S.N., "Geochronology investigation of the Bahlul Daghi volcanic dome, north of Tabriz, by application of 40Ar/39Ar dating on biotite (in Persian)", Iranian Journal of Crystallography and Mineralogy 27 (2) 2019) 375-384. [DOI:10.29252/ijcm.27.2.375]
7. [7] Ali Mousavi Z., Rezae Kahkhani M., "Biotite chemistery of Lakhasht granitoid )in Persian)", The 22th Symposium of Geological society of Iran, Shahid Beheshti University, Tehran, Iran (2014).
8. [8] Jamshidi Badr M., Khademi Parsa M., Masoudi F., "Determination of tectonic setting, mineralization and crystallization conditions of biotite in quartzdiorite from northeast of Delijan using biotite chemistry (in Persian)", Researches in Earth Sciences 12 (45) 86-100. [DOI:10.52547/esrj.12.1.86]
9. [9] Rasouli J., Ghorbani M., Ahadnejad V., "Mineral chemistry of Al in biotite for determination of temperature and pressure of copper mineralization in the Jebale Barez plutonic complex (in Persian)", Iranian Journal of Crystallography and Mineralogy 24 (1) (2016) 71-82.
10. [10] Kashtkar E., Ghorbani M., Omrani J., "Investigation on the mineral chemistry and the role of biotite total aluminum in detecting the type of mineralization in the intrusive bodies of Karaj-Taleghan axis (in Persian)", Iranian Journal of Crystallography and Mineralogy 25 (1) (2017) 13-24.
11. [11] Singha M., Singh L., "Vibrational spectroscopic study of muscovite and biotite layered phyllosilicates", Indian Journal of Pure & Applied Physics 54 (2016) 116-122.
12. [12] Hendricks S.B., Jefferson M.E., "Polymorphism of the micas with optical measurements", American Mineralogist (1939).
13. [13] Smith J.V., Yoder H.S., "Experimental and theoretical studies of the mica polymorphs". Mineralogical Magazine 31 (1956) 209-235. [DOI:10.1180/minmag.1956.031.234.03]
14. [14] Ross M., Takeda H., Wones D.R., "Mica polytypes: Systematic description and identification", Science 151 (1966) 191-193. [DOI:10.1126/science.151.3707.191]
15. [15] Takeda H., Ross M., "Mica polytypism: Dissimilarities in the crystal structures of coexisting lM and 2M1 biotite", American Mineralogist 60 (1975) 1030-1040.
16. [16] Soleimani Rad Z., Tondkar Sh., Mousavi Pak N., Masoudi F., " Introducing 2M1 hexagonal muscovite in the turquoise gemstone from Meydok, Kerman (in Persian)", The 22th Symposium of Geological society of Iran, Shahid Beheshti University, Tehran, Iran (2019).
17. [17] Tondkar Sh., Masoudi F., "Unite Cell Lattice Parameters for Hexagonal Mica from Borujerd Hornfels and Migmatites (in Persian)", the 28th Symposium of Crystallography and Mineralogy of Iran, Mashhad, Iran (2021).
18. [18] Donnay G., Donnay J.D.H., Takeda H., "Trioctahedral one-layer micas. II. Prediction of the structure from composition and cell dimensions", Acta Cryst 17 (1964) 1374-1381. [DOI:10.1107/S0365110X64003462]
19. [19] Bohlen S.R., Peacor D.R., Essene E.J., "Crystal chemistry of a metamorphic biotite and its significance in water barometry", American Mineralogist 65 (1980) 55-62.
20. [20] Takeda H., Morosin B., "Comparison of observed and predicted structural parameters of mica at high temperature", Acta Crystallographica B31 (1975) 2444-2452. [DOI:10.1107/S0567740875007777]
21. [21] Chon C.M., Kim S.A., Moon H.S., "Crystal structures of biotite at high temperatures and of heat-treated biotites using neutron powder diffraction", Clays and Clay Minerals 51 (5) (2003) 519-528. [DOI:10.1346/CCMN.2003.0510506]
22. [22] Nespolo M., Ferraris G., Takeda H., "Identification of two allotwins of mica polytypes in reciprocal space through the minimal rhombus unit", Acta Cryst B56 (2000) 639-647. [DOI:10.1107/S0108768100002044]
23. [23] Ohta T., Takeda H., Takeuochi H., "Mica polytypism: similarities in the crystal structures of coexisting 7M and 2M1 oxYbiotite", American Mineralogist 67 (1982) 298-310.
24. [24] Masoudi F., "Contact metamorphism and pegmatite development in the region SW, of Arak, Iran", Ph. D. theses, Leeds University, UK. Dept. of earth sciences (1997) 127p.
25. [25] Mahmoudi S., Corfu F., Masoudi F., Mehrabi B., Mohajjel M., "U-Pb dating and emplacement history of granitoid plutons in the northern Sanandaj-Sirjan Zone, Iran", Journal of Asian Earth Sciences 41 (2011) 238-249. [DOI:10.1016/j.jseaes.2011.03.006]
26. [26] Baharifar A.A, Pang K.N.A., Chung S.L., 2017. "Garnet-Amphibolites Mineralogy and thermobarometry in Aliabad-Damagh (south of Hamedan, Sanandaj-Sirjan Zone)", Petrology 8 (31) (2017).
27. [27] Takeuchi Y., Sadanaga R., "The crystal structure of xanthophyllite", Acta Crystallographica, 12 (1959) 945-946. [DOI:10.1107/S0365110X59002705]
28. [28] Radoslovich E.W., Norrish K., "The cell dimensions and symmetry of layer silicates. I. Some structural considerations", American Mineralogist 47 (1962) 599-616.
29. [29] Redfern S.A.T., Salje E., Maresch W., Schreyer W., "X-ray powder-diffraction and infrared study of the hexagonal to orthorhombic phase transition in K-bearing cordierite", American Mineralogist 74 (1989) 1293-1299.
30. [30] Finkelstein G., Dera P.K., Duffy T.S., "High-pressure phases of cordierite from single-crystal X-ray diffraction to 15 GPa", American Mineralogist 100 (2015) 1821-1833. [DOI:10.2138/am-2015-5073]
31. [31] Kloprogge T., Gaast S.V., Fredericks P.M., Frost R.L., Proceedings of the 12th International Clay Conference Bahai-Blanca, Argentina (2001).
32. [32] RRUFF, R040144, Powder Xray. Brinton's Quarry, Chester County, Pennsylvania, USA.
33. [33] RRUFF, R040144, Raman 532. Brinton's Quarry, Chester County, Pennsylvania, USA.
34. [34] RRUFF, R050068, Raman 532. S.W. Jasper County, Georgia, USA.
35. [35] RRUFF, R060204, Powder Xray. Mont Saint-Hilaire, Rouville County, Quebec, Canada.
36. [36] Ahmadi Khalaji A., Valizadeh M.V., Esmaeili D., "Petrology and geochemistry of the granitoid massif of Boroujerd (in Persian)", Journal of science (University of Tehran) 33 (1) (2007) 1-14.
37. [37] Ghasemi Siani M., Mehrabi B., Bayat S., Neubauer F., Cao Sh., "Geochronology, geochemistry and mineral chemistry of Malayer-Boroujerd-Shazand pegmatite dikes, Sanandaj-Sirjan zone, NW Iran", International Journal of Earth Sciences (2021). [DOI:10.1007/s00531-021-02009-9]
38. [38] Zare Shooli M., Tahmasbi Z., Saki A., Ahmadi Khalaji A., "The study of changing Rare Earth and Trace Elements to determine the origin of Borujerd migmatites (in Persian)", Iranian Journal of Crystallography and Mineralogy 27 (4) (2019) 941-958. [DOI:10.29252/ijcm.27.4.941]
39. [39] Mahmoudi Sh., Papi N., Baharifar A.A., "High-temperature metamorphism event in the East and North East Borujerd granite body from (in Persian)", Researches in earth sciences 9 (3) No. 35 (2018) 81-93.
40. [40] Vosoughi Abedini M., "Fundemental of theoretical and practical optical crystallography (in Persian)", Pars Geological Research Center (Arian Zamin) (2014) 308p.
41. [41] Sontevska V., Jovanovski G., Makreski P., Raskovska A., Soptrajanov B., Acta ChimSlov, 55 (2008) 757.
42. [42] Tahmasbi Z., Ahmadi Khalaji A., "Using of mineral chemistry to determine the formation conditions of Boroujerd granitoid complex and its metamorphic aureole (in Persian)", Petrology 6 (2) (2010) 77-95.
43. [43] Papi N., "Petrogenesis of granulite facies rocks in the contact aureole of Boroujerd complex (in Persian)", Msc thesis, Kharazmi University, Iran (2015).
44. [44] Heydarianmanesh A., Tahmasbi Z., Ahmadi Khalaji A., "Mineral chemistry and thermobarometry of migmatitic rocks of Boroujerd area (north of Sanandaj-Sirjan zone) (in Persian)", Petrology 8 (25) (2016) 117-139.
45. [45] Tondkar Sh., "Construction of metamorphic reactions in Borujerd granitoid metamorphic aureole based on algebraic analysis (in Persian)", Msc thesis, Shahid Beheshti University, Iran (2017). [DOI:10.29252/gnf.4.1.1]
46. [46] Malehmir Chegini S., "Phase equillibria in spinel and curundum bearing metamorphic rocks of Broujerd area (in Persian)", Msc thesis, Kharazmi University, Iran (2019).
47. [47] Zare Shooli M., Tahmasbi Z., Saki A., Ahmadi Khalaji A., "Mineral chemistry, pressure-temperature determination and fluids activities in Boroujerd migmatites using cordierite mineral (in Persian)", Iranian Journal of Crystallography and Mineralogy 27 (1) (2019) 135-150. [DOI:10.29252/ijcm.27.1.135]
48. [48] Takeda H., Burnham C.W., "Fluor-polylithionite: a lithium mica with nearly hexagonal (Si2O5)2− ring", Mineral. J. 6 (1969) 102-109. [DOI:10.2465/minerj1953.6.102]

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