Volume 25, Issue 3 (9-2017)                   www.ijcm.ir 2017, 25(3): 673-678 | Back to browse issues page

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Soleimannejad J, Sedghiniya S, Nasibipour M. Synthesis and Crystal Structure of bis(3,3,5,5-tetramethyl benzidinium) bis(pyridine-2,6-dicarboxylato) nickelate(II) monohydrate. www.ijcm.ir. 2017; 25 (3) :673-678
URL: http://ijcm.ir/article-1-965-en.html
Abstract:   (1362 Views)
The compound of (Htmb)2[Ni(pydc)­2)].H2O (1) (In that tmb and pydc are 3,3¢,5,5¢-tetramethyl benzidine and pyridine -2,6- dicarboxylic acid, respectively) was synthesized via the proton transfer method and the structure was determined by single crystal X-ray diffraction. This compound crystalized in monoclinic crystal system and C2/c space group. In the asymmetry unit of compound 1, there are half molecule of the [Ni(pydc)­2)]2- anionic complex, one protonated molecule of 3,3¢,5,5¢-tetramethyl benzidine as a counter ion and half of an uncoordinated water molecule. Extensive intermolecular N-H…O and O-H…N, hydrogen bonds along with π… π and C-H …π interactions contribute in self-assembly and formation of a novel supramolecular structure.
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Type of Study: Research | Subject: Special
Received: 2017/08/29 | Accepted: 2017/08/29 | Published: 2017/08/29

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