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Hasani F, Tabatabaee M, Sharif M, Mahmoodi M. Synthesis and structural characterization of cobalt (II) complex with Schiff base ligand encapsulated in Zeolite ZMS-5. www.ijcm.ir 2025; 33 (1) :153-160
URL: http://ijcm.ir/article-1-1769-en.html
URL: http://ijcm.ir/article-1-1769-en.html
1- Department of Chemistry, Yazd Branch, Islamic Azad University, Yazd, Iran
2- Department of Chemistry, Qom Branch, Islamic Azad University, Qom, Iran
3- Department of Biomedical Engineering, Yazd Branch, Islamic Azad University, Yazd, Iran
2- Department of Chemistry, Qom Branch, Islamic Azad University, Qom, Iran
3- Department of Biomedical Engineering, Yazd Branch, Islamic Azad University, Yazd, Iran
Abstract: (141 Views)
In this research, zeolite ZMS-5 was synthesized by hydrothermal method and ion-exchanging of Na+ with Co2+ within the zeolite was occurred. Schiff- base ligand (L) (L= 6,6'-((1E,1'E)-(ethane-1,2-diylbis(azanylylidene))bis(methanylylidene))bis(2-methoxyphenol)) was prepared with the reaction of 2-Hydroxy-3-methoxybenzaldehyde and ethylenediamine. The flexible ligand (FL) method was used for the capsulated of complex into of the zeolite cage. The structure of capsulated zeolite with Co-L complex was characterized by FT-IR and XRD, and the size and morphology of compound was determined with SEM.
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